PREPARATION OF [NP(P-OC6H4LI)2]3 BY METAL-HALOGEN EXCHANGE, AND ITS REACTIONS WITH ELECTROPHILES

被引：21

作者：

EVANS, TL ^{[1
]}

FULLER, TJ ^{[1
]}

ALLCOCK, HR ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 01期

关键词：

D O I：

10.1021/ja00495a052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of cyclic and polymeric halophosphazenes with organolithium reagents have been studied extensively, 1-3 but the reactions of organometallic reagents with cyclic and polymeric organo-functional phosphazenes have not been explored in detail. Of particular interest to us were reactions that could yield carbanionic species bound directly to phosphazene cyclic and polymeric compounds. Such reactive intermediates could be used to synthesize a wide range of new cyclic and high polymeric phosphazenes not accessible by other synthetic routes, including those that might form unusual ligands for transiten metals. © 1979, American Chemical Society. All rights reserved.

引用

页码：242 / 242

页数：1

共 8 条

[1] SYNTHESIS OF ALKYL AND ARYL PHOSPHAZENE HIGH POLYMERS [J].