Crystal structure of meso-tetrakis(4-nitrophenyl) porphyrin nitrobenzene disolvate

被引：3

作者：

Seredyuk, Maksym ^{[1
]}

Gumienna-Kontecka, Elzbieta ^{[2
]}

Brzuszkiewicz, Anna ^{[2
]}

Iskenderov, Turganbay S. ^{[1
]}

Kalibabchuk, Valentina A. ^{[3
]}

机构：

[1] Natl Taras Shevchenko Univ, Dept Chem, Volodymyrska Str 64, UA-01601 Kiev, Ukraine

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[3] OO Bohomolets Natl Med Univ, Dept Gen Chem, UA-01004 Kiev, Ukraine

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; porphyrins; hydrogen bonding; supramolecular chains;

D O I：

10.1107/S1600536814021503

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The porphyrin core of the title centrosymmetric compound, C44H26N8O8 center dot 2C(6)H(5)NO(2), is approximately planar, the maximum deviation being 0.069 (3) angstrom. The planes of the benzene rings of the nitrophenyl substituents are almost perpendicular to the porphyrin mean plane, making dihedral angles of 73.89 (9) and 89.24 (9)degrees. The two pyrrole ring H atoms are equally disordered over the four pyrrole ring N atoms. In the crystal, weak C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds link the porphyrin molecules into a threedimensional supramolecular network. The nitrobenzene solvent molecules are linked by weak C-H center dot center dot center dot O hydrogen bonds into supramolecular chains propagating along the a-axis direction.

引用

页码：O1147 / +

页数：11

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