ANALYSIS OF ANIONS IN RAIN WATER BY CAPILLARY ELECTROPHORESIS

被引:0
|
作者
NGUYEN, HMYL
TAMISIERKAROLAK, SL
CZOK, M
LAUGIER, R
CARDOT, P
机构
[1] LAB HYDROL,CHILLY MAZARIN,FRANCE
[2] FAC PHARM CHATENAY MALABRY,CHIM ANALYT & ELECTROCHIM ORGAN LAB,5 RUE JB CLEMENT,F-92290 CHATENAY MALABRY,FRANCE
关键词
CAPILLARY ELECTROPHORESIS; ANION; BRAIN WATER; SOLVENT STACKING; LIMIT OF QUANTIFICATION;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A method for the separation of inorganic anions by capillary zone electrophoresis is presented and applied to the determination of chloride, nitrite, nitrate, and sulfate in rain water samples. Direct injection of samples without addition of buffer leads to a significant increase of sensitivity due to solvent stacking, but the calibration curves are non-linear and display a poor reproducibility. Using chlorate as internal standard, linear calibration curves are obtained with an accuracy of better than 10%.
引用
收藏
页码:82 / 87
页数:6
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