SYNTHESIS AND ACYLATION OF ALLYLIC MERCURIC IODIDES - A CONVENIENT SYNTHESIS OF ALLYLIC KETONES

被引：26

作者：

LAROCK, RC

LU, YD

机构：

[1] Department of Chemistry, Iowa State University, Ames

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 10期

关键词：

D O I：

10.1021/jo00062a031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic mercuric iodides are readily prepared by the reaction of mercury(0) and allylic iodides. They undergo efficient acylation with allylic rearrangement upon reaction with acyl chlorides and aluminum chloride to provide a convenient synthesis of allylic ketones. Artemisia ketone is prepared in two steps by this approach.

引用

页码：2846 / 2850

页数：5

共 63 条

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