A SIMPLE-MODEL FOR DEUTERIUM CROSS-POLARIZATION MAGIC-ANGLE-SPINNING NUCLEAR-MAGNETIC-RESONANCE AT THE INTERPHASES OF AMORPHOUS MATERIALS

被引：3
作者：
ZUMBULYADIS, N
机构：
[1] Analytical Technology Division, Eastman Kodak Company
来源：
SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1995年 / 5卷 / 01期
关键词：
CROSS-POLARIZATION; MAGIC-ANGLE SPINNING; H-2 NUCLEAR MAGNETIC RESONANCE; INTERPHASES; IMMISCIBLE PHASES;
D O I：
10.1016/0926-2040(95)00038-R
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structure and composition of the interphase at the boundary of two immiscible phases has long been the subject of experimental and theoretical studies in polymer science. Cross-polarization between protons and deuterons offers the potential for elucidating the composition of the interphase if one of the immiscible phases is deuterated. A prerequisite for such an analysis is the establishment of an experimental protocol for reliable spin counting in H-1-H-2 cross-polarization magic-angle spinning (CP-MAS) spectroscopy. In this paper we present a simple model for the quantitative analysis of deuterium CP-MAS spectra. The model will be applied to the characterization of the polystyrene-b-poly(methyl methacrylate) interphase in a subsequent publication.
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页码：3 / 7
页数：5
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