LOW-VALENT TITANIUM REDUCTIVE ELIMINATION - A DIRECT AND HIGHLY STEREOSELECTIVE SYNTHESIS OF VITAMIN-A ALDEHYDE

被引：10

作者：

SOLLADIE, G

BERL, V

机构：

[1] Ecole Européenne des Hautes Etudes, Industries Chimiques Laboratoire, Stéréochimie associé au CNRS, 1 Rue Blaise Pascal F

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)92667-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was shown that the low-valent titanium reductive elimination could be carried out in presence of a thioacetal group. An application to the synthesis of vitamin A aldehyde is described.

引用

页码：3477 / 3480

页数：4

共 6 条

[1] PHOTOCHEMISTRY AND SYNTHESIS OF STEREOISOMERS OF VITAMIN-A [J].

LIU, RSH ;

ASATO, AE .

TETRAHEDRON, 1984, 40 (11) :1931-1969

[2] NEW METHOD FOR REDUCTIVE COUPLING OF CARBONYLS TO OLEFINS - SYNTHESIS OF BETA-CAROTENE [J].

MCMURRY, JE ;

FLEMING, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (14) :4708-4709

[3] SYNTHESIS OF NEW AROMATIC RETINOID ANALOGS BY LOW-VALENT TITANIUM INDUCED REDUCTIVE ELIMINATION [J].

SOLLADIE, G ;

GIRARDIN, A ;

LANG, G .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (11) :2620-2628

[4]

SOLLADIE G, 1991, SYNLETT, P795

[5]

TAMURA Y, 1973, SYNTHESIS-STUTTGART, P312

[6] TITANIUM-INDUCED REDUCTIVE ELIMINATION - SYNTHESES OF 1,3-DIENES [J].

WALBORSKY, HM ;

WUST, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5807-5808

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