DONNAN PHENOMENA IN THE PROTON DOPING OF EMERALDINE

被引：39

作者：

CHARTIER, P

MATTES, B

REISS, H

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

[2] UNIV STRASBOURG 1,ELECTROCHIM & CHIM PHYS CORPS SOLIDE LAB,CNRS,URA 405,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 08期

关键词：

D O I：

10.1021/j100187a068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of NaCl on proton uptake by emeraldine base from HCl solutions was investigated by means of conductivity measurements of emeraldine films which were immersed in HCl + NaCl solutions at various pH's and concentrations. A theory, based on the thermodynamics of phase equilibria in the absence and in the presence of NaCl, leads to the right order of magnitude of the observed effects and supports the existence of a modified Donnan phenomenon.

引用

页码：3556 / 3560

页数：5

共 12 条

[1]

ALIX A, 1989, SYNTHETIC MET, V29, pE457

[2] CONJUGATED POLYMER-FILMS FOR GAS SEPARATIONS [J].

ANDERSON, MR ;

MATTES, BR ;

REISS, H ;

KANER, RB .

SCIENCE, 1991, 252 (5011) :1412-1415

[3]

[Anonymous], 1970, ACIDITY FUNCTIONS

[4]

CHAING JC, 1986, SYNTHETIC MET, V13, P193

[5] POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].

CHIANG, JC ;

MACDIARMID, AG .

SYNTHETIC METALS, 1986, 13 (1-3) :193-205

[6]

GINDER JM, 1989, SYNTHETIC MET, V29, pE395, DOI 10.1016/0379-6779(89)90324-X

[7] POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].

HUANG, WS ;

HUMPHREY, BD ;

MACDIARMID, AG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&

[8] POLYANILINE - A NEW CONCEPT IN CONDUCTING POLYMERS [J].

MACDIARMID, AG ;

CHIANG, JC ;

RICHTER, AF ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1987, 18 (1-3) :285-290

[9] POLYANILINE - INTERCONVERSION OF METALLIC AND INSULATING FORMS [J].

MACDIARMID, AG ;

CHIANG, JC ;

HALPERN, M ;

HUANG, WS ;

MU, SL ;

SOMASIRI, NLD ;

WU, WQ ;

YANIGER, SI .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4) :173-180

[10]

NCHTSCHEIN, 1989, SYNTHETIC MET, V29, pE211

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