THIOLATE ANION AS A NUCLEOPHILE .9. REACTIONS OF SOME FLUOROAROMATICS

被引：18
作者：
PEACH, ME
RAYNER, ES
机构：
[1] Chemistry Department, Acadia University, Wolfville
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 13卷 / 05期
关键词：
D O I：
10.1016/S0022-1139(00)81580-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of some halogenoaromatic compounds, mainly fluoroaromatics C6FxH6-x with the methanethiolate anion have been studied in DMF or an HMPA/THF mixture. Complete replacement of fluorine occurred forming C6(SMe)xH6-x. Attempts to prepare C6(SEt)6 and compounds such as C6(SEt)2(SMe)4 are described. Other new compounds isolated included C6(SMe)5SH and C6F2(SMe)2(SEt)2. Details of the spectra, particularly NMR, are given. © 1979.
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页码：447 / 454
页数：8
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