THE 1ST EXAMPLE OF A CYCLOOCTA-1,3-DIENE LIGAND BOUND TO RHODIUM - CRYSTAL-STRUCTURES OF RH(ETA-5-C5PH5)L (L = 1,3- OR 1,5-C8H12)

被引:13
作者
BAGHDADI, J [1 ]
BAILEY, NA [1 ]
DOWDING, AS [1 ]
WHITE, C [1 ]
机构
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
关键词
D O I
10.1039/c39920000170
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Under reducing conditions [Rh(eta(5)-C5Ph5)Br2]2 reacts with either cycloocta-1,3- or -1,5-diene to give predominantly Rh(eta(5)-C5Ph5)(1,3-C8H12) 1 together with a small amount (less-than-or-equal-to 15%) of Rh(eta(5)-C5Ph5)(1,5-C8H12) 2.
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页码:170 / 171
页数:2
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