VIBRATIONAL KINETICS OF SF6 DISSOLVED IN SIMPLE CRYOGENIC LIQUIDS

被引：28

作者：

BRUECK, SRJ

DEUTSCH, TF

OSGOOD, RM

机构：

[1] Lincoln Laboratory, Massachusetts Institute of Technology, Lexington

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 60卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)80024-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Both linear and infrared-infrared double resonance measurements of the ν3 absorption band of SF6 dissolved in liquid O2 and Ar are reported. Saturation measurements of the infrared absorption give a V-T relaxation time of 27 ± 7 ps in liquid O2 and 160 ± 40 ps in liquid Ar. The unique features of the spectroscopy of complex molecules in simple liquid hosts offer potential advantages for laser photochemistry. © 1979.

引用

页码：242 / 246

页数：5

共 17 条

[1]

Bertsev V. V., 1974, Optics and Spectroscopy, V37, P263

[2] VIBRATIONAL ENERGY RELAXATION OF CH3F DISSOLVED IN LIQUID O-2 AND AR [J].