STRUCTURAL AND OPTICAL PROPERTIES OF UNDOPED AND Co DOPED ZnO NANOSTRUCTURED THIN FILMS

被引:0
作者
Murugesan, Nirmala [1 ]
Achuthanunni, Anukaliani [1 ]
机构
[1] Kongunadu Coll Arts & Sci, PG & Res Dept Phys, Coimbatore 641029, Tamil Nadu, India
来源
SURANAREE JOURNAL OF SCIENCE AND TECHNOLOGY | 2011年 / 18卷 / 01期
关键词
Zinc oxide; sol-gel; dip coating; thin film;
D O I
暂无
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this study ZnO:Co nano structured thin films doped with cobalt at different concentrations were deposited on glass substrates by the sol-gel dip coating method. Characterization techniques of XRD, SEM with EDAX, and UV-Visible spectra measurements were done to investigate the effects of the Co doping concentration on the optical and structural properties of the ZnO:Co nano structured thin films. The XRD patterns of all nano structured films show the crystalline behavior and are of a hexagonal wurtzite structure. Our results reveal that, with a high percent of cobalt, not only the degree of the crystalline behavior but also a broadening of the peak occurs. The compositional analysis was carried out by energy dispersive X-ray (EDX) measurement. The optical studies show that the band gap of ZnO:Co decreases the d electron of the Co atom and band carriers of the host material. This unique property of ZnCoO films can be used to fabricate transparent electrodes in flat panel displays and metal-insulator-semiconductor diodes.
引用
收藏
页码:81 / 88
页数:8
相关论文
共 21 条
[1]   Cobalt substituted ZnO thin films: a potential candidate for spintronics [J].
Bhatti, Kanwal Preet ;
Malik, Vivek Kumar ;
Chaudhary, Sujeet .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2008, 19 (8-9) :849-854
[2]   Cobalt-doped ZnO - a room temperature dilute magnetic semiconductor [J].
Fitzgerald, CB ;
Venkatesan, M ;
Lunney, JG ;
Dorneles, LS ;
Coey, JMD .
APPLIED SURFACE SCIENCE, 2005, 247 (1-4) :493-496
[3]   Electrical, structural and morphological properties of chemically sprayed F-doped ZnO films:: effect of the ageing-time of the starting solution, solvent and substrate temperature [J].
Guillén-Santiago, A ;
Olvera, MDL ;
Maldonado, A ;
Asomoza, R ;
Acosta, DR .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (05) :952-959
[4]   Structure and Morphology of Nanostructured Zinc Oxide Thin Films Prepared by Dip- vs. Spin-Coating Methods [J].
Habibi, M. H. ;
Sardashti, M. Khaledi .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2008, 5 (04) :603-609
[5]   Structural and electrical properties of ZnO films prepared by screen printing technique [J].
Ismail, B ;
Abaab, M ;
Rezig, B .
THIN SOLID FILMS, 2001, 383 (1-2) :92-94
[6]   Structure and magnetism of cobalt-doped ZnO thin films [J].
Ivill, M. ;
Pearton, S. J. ;
Rawal, S. ;
Leu, L. ;
Sadik, P. ;
Das, R. ;
Hebard, A. F. ;
Chisholm, M. ;
Budai, J. D. ;
Norton, D. P. .
NEW JOURNAL OF PHYSICS, 2008, 10
[7]   Magnetic properties of epitaxially grown semiconducting Zn1-xCoxO thin films by pulsed laser deposition [J].
Kim, JH ;
Kim, H ;
Kim, D ;
Ihm, YE ;
Choo, WK .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (10) :6066-6071
[8]   The effect of Mn2+ doping on strcuture and photoluminescence of ZnO nanofilms synthesized by sol-gel method [J].
Li, J. H. ;
Shen, D. Z. ;
Zhang, J. Y. ;
Zhao, D. X. ;
Li, B. S. ;
Lu, Y. M. ;
Liu, Y. C. ;
Fan, X. W. .
JOURNAL OF LUMINESCENCE, 2007, 122 (352-354) :352-354
[9]   Donor defects enhanced ferromagnetism in Co:ZnO films [J].
Liu, X. J. ;
Song, C. ;
Zeng, F. ;
Pan, F. .
THIN SOLID FILMS, 2008, 516 (23) :8757-8761
[10]   Thickness dependence of ZnO:In thin films doped with different indium compounds and deposited by chemical spray [J].
Lucio-Lopez, M. A. ;
Maldonado, A. ;
Castanedo-Perez, R. ;
Torres-Delgado, G. ;
Olvera, M. de la L. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (15) :2362-2376