CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS

被引：645

作者：

IRIE, R ^{[1
]}

NODA, K ^{[1
]}

ITO, Y ^{[1
]}

MATSUMOTO, N ^{[1
]}

KATSUKI, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)88562-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Manganese complex of the optically active salen ligand [N,N'-bis[(S)-3-(1-phenylpropyl)salicylidene]-(1R,2R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for (E)-1-phenyl-1-propene. © 1990.

引用

页码：7345 / 7348

页数：4

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