7-CIS-3-DEYDRORETINAL AND 7,9-DICIS-3-DEHYDRORETINAL - HINDERED ISOMERS OF VITAMIN-A(2) ALDEHYDE

被引：4

作者：

CHEN, RL ^{[1
]}

LIU, RSH ^{[1
]}

机构：

[1] UNIV HAWAII, DEPT CHEM, HONOLULU, HI 96822 USA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73404-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Successful synthesis of the hindered 7-cis and 7,9-dicis isomers of 3-dehydroretinal from beta-ionone is reported. The procedure, involving introduction of the hindered 7-cis geometry prior to the 3,4-double bond, should be applicable to preparation of other unknown isomers of Vitamin Aa aldehyde.

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页码：6251 / 6254

页数：4

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