STRUCTURE OF AN ADENINE HYDROGEN-PEROXIDE ADDUCT

被引：20

作者：

SERRA, MA ^{[1
]}

DORNER, BK ^{[1
]}

SILVER, ME ^{[1
]}

机构：

[1] HOPE COLL,DEPT CHEM,HOLLAND,MI 49423

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192002294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C5H5N5.H2O2, M, = 169.14, monoclinic, C2/c, a = 8.939 (3), b = 10.697 (4), c = 14.920 (4) angstrom, beta = 102.55 (2)-degrees, V = 1392.5 (7) angstrom3, Z = 8, D(x) = 1.614 g cm-3, lambda(Mo Kalpha1) = 0.71069 angstrom, mu = 1.209 cm-1, F(000) = 704, T = 293 K, final R = 0.047 for 1090 observations. Each hydrogen peroxide molecule hydrogen bonds with three adjacent adenine molecules. Hydrogen bonding also occurs between N(9)-H(N9) and N(3) of an inversion related molecule. Molecules from adjacent planes are related by a non-crystallographic inversion center and exhibit strong stacking interactions along the b axis [planar separation 3.283 (3) angstrom].

引用

页码：1957 / 1960

页数：4

共 14 条

[1]

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[2]

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