SYNTHESIS OF PHOSPHAPROPYNE BY FLASH THERMOLYSIS OF 1-VINYLPHOSPHIRANE OR DIVINYLPHOSPHINE

被引：28

作者：

HABER, S ^{[1
]}

LEFLOCH, P ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,HETEROATOMES & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermolysis of 1-vinylphosphirane 5 at 700-degrees-C yields phosphapropyne 7; owing to the existence of an equilibrium between divinylphosphine 6 and 1-vinylphosphirane above 500-degrees-C, the same phosphapropyne is also obtained by thermolysis of divinylphosphine.

引用

页码：1799 / 1800

页数：2