SYNTHESIS OF PHOSPHAPROPYNE BY FLASH THERMOLYSIS OF 1-VINYLPHOSPHIRANE OR DIVINYLPHOSPHINE

被引：28

作者：

HABER, S ^{[1
]}

LEFLOCH, P ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,HETEROATOMES & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermolysis of 1-vinylphosphirane 5 at 700-degrees-C yields phosphapropyne 7; owing to the existence of an equilibrium between divinylphosphine 6 and 1-vinylphosphirane above 500-degrees-C, the same phosphapropyne is also obtained by thermolysis of divinylphosphine.

引用

页码：1799 / 1800

页数：2

共 11 条

[1]

FUCHS EPO, 1987, J ORGANOMET CHEM, V338, P329

[2] SYNTHESIS OF NONSTABILIZED PHOSPHAALKYNES BY VACUUM GAS-SOLID HCL ELIMINATION [J].

GUILLEMIN, JC ;

JANATI, T ;

GUENOT, P ;

SAVIGNAC, P ;

DENIS, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (02) :196-198

[3] LEWIS BASE-INDUCED REARRANGEMENT OF PRIMARY ETHYN-1-YLPHOSPHINES, A NEW AND EFFICIENT ROUTE TO PHOSPHAALKYNES [J].

GUILLEMIN, JC ;

JANATI, T ;

DENIS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (05) :415-416

[4]

HERMESDORF M, 1989, PHOSPHORUS SULFUR, V46, P31

[5] DETECTION OF REACTIVE MOLECULE 1-PHOSPHAPROPYNE, CH3C=P, BY MICROWAVE SPECTROSCOPY [J].

HOPKINSON, MJ ;

KROTO, HW ;

NIXON, JF ;

SIMMONS, NPC .

CHEMICAL PHYSICS LETTERS, 1976, 42 (03) :460-461

[6]

LEFLOCH P, 1991, SYNLETT, P743

[7]

LI X, 1992, 12TH ICPC TOUL

[8] CHEMISTRY OF 3-MEMBERED CARBON PHOSPHORUS-HETEROCYCLES [J].

MATHEY, F .

CHEMICAL REVIEWS, 1990, 90 (06) :997-1025

[9]

MATVEEV IS, 1974, ZH STRUKT KHIM, V15, P145

[10] AN ABINITIO STUDY OF THE ELECTRONIC-STRUCTURE OF THE GROUND TRIPLET AND LOW-LYING SINGLET-STATES OF FORMYLNITRENE, HCON, AND FORMYLPHOSPHINIDENE, HCOP [J].

MAVRIDIS, A ;

HARRISON, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) :7651-7655

← 1 2 →