SYNTHESIS AND X-RAY STRUCTURE OF (-)-[MO(ETA-5-C5ME4-3-PINANYL)(CO)3ME]

被引：9

作者：

LAI, R ^{[1
]}

BOUSQUET, L ^{[1
]}

HEUMANN, A ^{[1
]}

机构：

[1] UNIV MARSEILLE,FAC ST JEROME,URA 1410,ENSSPICAM,F-13013 MARSEILLE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 444卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83063-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the methyl ester of (-)-pinane-3-carboxylic acid 1 with the lithium derivative of 2-brombut-2-ene affords, after dehydration, an isomeric mixture of 3-pinanyl cyclopentadienes 3. Successive treatment with Li(n)Bu, Mo(CO)6 and Mel gives rise to the title complex 5, whose NMR spectra and X-ray structure unambiguously demonstrate the optical integrity and purity of this compound.

引用

页码：115 / 119

页数：5

共 22 条

[1] 1,3-AMINOALCOHOLS BY REDUCTIVE CLEAVAGE OF ISOXAZOLIDINES WITH MOLYBDENUM HEXACARBONYL
CICCHI, S
GOTI, A
BRANDI, A
GUARNA, A
DESARLO, F
[J]. TETRAHEDRON LETTERS, 1990, 31 (23) : 3351 - 3354
[2] COLETTI S, 1991, ORGANOMETALLICS, V10, P3438
[3] COLETTI SL, 1989, TETRAHEDRON LETT, V30, P3513
[4] COLETTI SL, 1992, ORGANOMETALLICS, V11, P980
[5] ENANTIOSELECTIVE HOMOGENEOUS CATALYSIS INVOLVING TRANSITION-METAL ALLYL INTERMEDIATES
CONSIGLIO, G
WAYMOUTH, RM
[J]. CHEMICAL REVIEWS, 1989, 89 (01) : 257 - 276
[6] SYTHESIS OF AN OPTICALLY-ACTIVE PENTAALKYL CYCLOPENTADIENYL LIGAND - APPLICATIONS IN ORGANOMETALLIC CHEMISTRY
DORMOND, A
ELBOUADILI, A
MOISE, C
[J]. TETRAHEDRON LETTERS, 1983, 24 (30) : 3087 - 3090
[7] ENANTIOSELECTIVE CATALYSIS WITH A NEW ZIRCONIUM TRICHLORIDE LEWIS ACID CONTAINING A DIBORNACYCLOPENTADIENYL LIGAND
ERKER, G
VANDERZEIJDEN, AAH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (05): : 512 - 514
[8] STEREOSELECTIVE ORGANIC-REACTIONS - CATALYSTS FOR CARBONYL ADDITION PROCESSES
EVANS, DA
[J]. SCIENCE, 1988, 240 (4851) : 420 - 426
[9] Frenz B.A, 1978, COMPUTING CRYSTALLOG, P64
[10] SYNTHESIS AND ASYMMETRIC REACTIVITY OF ENANTIOMERICALLY PURE CYCLOPENTADIENYLMETAL COMPLEXES DERIVED FROM THE CHIRAL POOL
HALTERMAN, RL
VOLLHARDT, KPC
[J]. ORGANOMETALLICS, 1988, 7 (04) : 883 - 892

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