SYNTHESES OF ENANTIOMERICALLY PURE FURYL AND THIENYL PARA-TOLYL SULFOXIDES

被引：20

作者：

GIRODIER, L ^{[1
]}

MAIGNAN, C ^{[1
]}

ROUESSAC, F ^{[1
]}

机构：

[1] UNIV MAINE,CNRS,SYNTHESE ORGAN LAB,AVE O MESSIAEN,F-72017 LE MANS,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)82183-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report a highly enantioselective reaction of Grignard reagents, derived from simple furans or thiophene, with (-)-(S)-menthylsulfinate to give in high yield enantiomerically pure furyl and thienylsulfoxides.

引用

页码：857 / 858

页数：2

共 4 条

[1] CONFIGURATIONAL RELATIONSHIPS AMONG SOME SULFOXIDES [J].

ANDERSEN, KK .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (07) :1953-&

[2] 1ST SYNTHESES OF CHIRAL 2-SULFINYLBUTADIENES [J].

BONFAND, E ;

GOSSELIN, P ;

MAIGNAN, C .

TETRAHEDRON LETTERS, 1992, 33 (17) :2347-2348

[3]

BRANDSMA L, 1987, PREPARATIVE POLAR OR, V1, P158

[4] EXPERIMENTS IN FURAN SERIES .12. PREPARATION OF 3-FURYL KETONES [J].

SROGL, J ;

JANDA, M ;

STIBOR, I .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1970, 35 (11) :3478-&

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