MODULATED MOLECULAR-BEAM SCATTERING FROM SOLID-SURFACES - PULSE TESTING METHOD OF ANALYSIS

被引：4

作者：

CHANG, HC ^{[1
]}

WEINBERG, WH ^{[1
]}

机构：

[1] CALTECH,DIV CHEM & CHEM ENGN,PASADENA,CA 91125

来源：

APPLIED SURFACE SCIENCE | 1979年 / 3卷 / 02期

关键词：

D O I：

10.1016/0378-5963(79)90017-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mathematical formalism is presented [the pulse testing (PT) method] with which it is possible to use the entire shape of the reactant and product beams in modulated molecular beam mass spectrometry in order to derive kinetic parameters of various surface processes. The advantages of the PT method compared to the more traditional frequency response (FR) method (in which only the first Fourier coefficients of the reactant and product beams are utilized) are discussed. The adsorption and decomposition of formic acid on a Ni(110) surface are analyzed in order to illustrate the ease with which the PT method may be applied. © 1979.

引用

页码：168 / 178

页数：11

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