PENTADIENYL-METAL PHOSPHINE CHEMISTRY .26. PHOSPHAPENTADIENYL-IRIDIUM-PHOSPHINE CHEMISTRY - SYNTHESIS, STRUCTURE, AND SPECTROSCOPY OF (MU-ETA-1-PHOSPHAPENTADIENYL)2IR2(PET3)4

被引：18

作者：

BLEEKE, JR

ROHDE, AM

ROBINSON, KD

机构：

[1] Department of Chemistry, Washington University, St. Louis

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of an anionic phosphapentadienide reagent, lithium phosphapentadienide has been isolated and spectroscopically characterized. Reaction of this species with (Cl)Ir(PEt3)3 yielded the phosphido-bridged iridium dimer (mu-eta1-phosphapentadienyl)2Ir2(PEt3)4 as trans and cis isomers (1a and 1b, respectively). An X-ray crystal structure of 1a has been obtained.

引用

页码：401 / 403

页数：3

共 50 条

[21] STRUCTURAL CHEMISTRY OF TITANIUM AND ALUMINUM BIMETALLIC HYDRIDE COMPLEXES .3. SYNTHESIS, MOLECULAR-STRUCTURE AND CATALYTIC PROPERTIES OF "[(ETA-5-C5H5)2TI(MU-2-H)2AL(MU-2-H) (ETA-1-ETA-5-C5H4)TI(ETA-5-C5H5)-(MU-2-H)]2.C6H5CH3
LOBKOVSKII, EB
SOLOVEICHIK, GL
SIZOV, AI
BULYCHEV, BM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (01) : 53 - 66
[22] METAL-TETRATHIOLENE CHEMISTRY - 1ST DISULFUR BRIDGE IN THE NOVEL DI-IRIDIUM CLUSTER (PH3P)2(CO)2BR2IR2(C10H4S4) - X-RAY CRYSTAL-STRUCTURE
TEO, BK
SNYDERROBINSON, PA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (06) : 255 - 256
[23] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .66. CARBABORANETUNGSTEN-PLATINUM COMPLEXES - POLYHEDRAL REARRANGEMENTS OF A 12-VERTEX CAGE SYSTEM - CRYSTAL-STRUCTURES OF [PTW(CO)2-(PET3)2(ETA-6-C2B9H8(CH2C6H4ME-4)ME2)].CH2CL2,[PTW(MU-H)(MU-SIGMA-ETA-5-C2B9H7(CH2C6H4-ME-4)ME2)(CO)2(PME3)(PET3)2], AND RELATED-COMPOUNDS
ATTFIELD, MJ
HOWARD, JAK
JELFS, AND
NUNN, CM
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (09): : 2219 - 2233
[24] THE CARBABORANE GROUP ETA-5-C2B9H9ME2 AS A SPECTATOR AND NON-SPECTATOR LIGAND IN DI-METAL AND TRI-METAL COMPLEX CHEMISTRY - X-RAY CRYSTAL-STRUCTURES OF [PPH4][CO2W(MU-3-CPH)(CO)8(ETA-5-C2B9H9ME2)].1/2-CH2CL2, [NET4][FEW(MU-CC6H3ME2-2,6)(CO)5-(ETA-5-C2B9H9ME2)], AND [IRW(MU-CC6H4ME-4)(CO)2(PET3)2(ETA-5-C2B9H9ME2)]T
BAUMANN, FE
HOWARD, JAK
MUSGROVE, RJ
SHERWOOD, P
RUIZ, MA
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (24) : 1881 - 1884
[25] CLUSTER CHEMISTRY .30. REACTION OF A TRIRUTHENIUM ANION WITH [O[AU(PPH3)]3][BF4] - SYNTHESIS AND STRUCTURE OF RU3AU3(MU-3-2-ETA-1,ETA-3-C12H15)(CO)8(PPH3)3
BRUCE, MI
SHAWKATALY, OB
NICHOLSON, BK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 275 (02) : 223 - 232
[26] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .49. SYNTHESIS OF MIXED-METAL COMPLEXES WITH BONDS BETWEEN CR,MO OR W AND CO, RH, IR OR RE - CRYSTAL-STRUCTURE OF [CRRERH2(MU-3CC6H4ME-4)-(MU-CO)(CO)9(ETA-C9H7)2]
ABAD, JA
DELGADO, E
GARCIA, ME
GROSSEOPHOFF, MJ
HART, IJ
JEFFERY, JC
SIMMONS, MS
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (01): : 41 - 50
[27] CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .18. SYNTHESIS OF THE COMPLEXES [MW(MU-CC6H4ME-4)(MU-(SIGMA-ETA-2-CO))(CO)(ETA-C5H5)3](M= TI OR ZR) AND THE CRYSTAL-STRUCTURE OF THE TITANIUM TUNGSTEN COMPOUND
DAWKINS, GM
GREEN, M
MEAD, KA
SALAUN, JY
STONE, FGA
WOODWARD, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (03): : 527 - 530
[28] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .93. SYNTHESIS OF HETEROPOLYNUCLEAR METAL-COMPOUNDS WITH CHAINS OF 7 TO 11 METAL ATOMS - CRYSTAL-STRUCTURE OF [MO2W3PT6(MU-3-CME)3(MU-3-CC6H4ME-4)2(CO)10(PME2PH)4(ETA-C5H5)5]
DAVIES, SJ
HOWARD, JAK
MUSGROVE, RJ
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (11): : 2269 - 2279
[29] CHEMISTRY OF PHOSPHIDO-BRIDGED DIMOLYBDENUM COMPLEXES .1. HIGH-YIELD SYNTHESIS OF [MO2(ETA-5-C5H5)2(MU-H)(MU-PPH2)(CO)4] AND ITS REACTIONS WITH ORGANO-PHOSPHORUS LIGANDS - X-RAY CRYSTAL-STRUCTURE OF [MO2(ETA-5-C5H5)2(MU-H)-(MU-PPH2)(CO)3(P(OME)3)]
HENRICK, K
MCPARTLIN, M
HORTON, AD
MAYS, MJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (04): : 1083 - 1088
[30] CHEMISTRY OF IRIDIUM CARBONYL CLUSTERS - SYNTHESIS AND CHEMICAL CHARACTERIZATION OF THE HEXANUCLEAR ANIONS [IR6(CO)15(CO2ME)]-, [IR6(CO)15(CO2ET)] AND [IR6(CO)14(CO2ME))2]2- - CRYSTAL AND MOLECULAR-STRUCTURE OF [N(PPH3)2][IR6(MU-CO)4(CO)11(CO2ME)]
GARLASCHELLI, L
MALATESTA, MC
MARTINENGO, S
DEMARTIN, F
MANASSERO, M
SANSONI, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (04): : 777 - 782

← 1 2 3 4 5 →