PENTADIENYL-METAL PHOSPHINE CHEMISTRY .26. PHOSPHAPENTADIENYL-IRIDIUM-PHOSPHINE CHEMISTRY - SYNTHESIS, STRUCTURE, AND SPECTROSCOPY OF (MU-ETA-1-PHOSPHAPENTADIENYL)2IR2(PET3)4

被引：18

作者：

BLEEKE, JR

ROHDE, AM

ROBINSON, KD

机构：

[1] Department of Chemistry, Washington University, St. Louis

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of an anionic phosphapentadienide reagent, lithium phosphapentadienide has been isolated and spectroscopically characterized. Reaction of this species with (Cl)Ir(PEt3)3 yielded the phosphido-bridged iridium dimer (mu-eta1-phosphapentadienyl)2Ir2(PEt3)4 as trans and cis isomers (1a and 1b, respectively). An X-ray crystal structure of 1a has been obtained.

引用

页码：401 / 403

页数：3

共 50 条

[1] PHOSPHAPENTADIENYL-IRIDIUM-PHOSPHINE CHEMISTRY - SYNTHESIS, STRUCTURE, AND SPECTROSCOPY OF PHOSPHAPENTADIENYL-BRIDGED IRIDIUM DIMERS
BLEEKE, JR
ROHDE, AM
ROBINSON, KD
ORGANOMETALLICS, 1995, 14 (04) : 1674 - 1680
[2] Phosphapentadienyl-iridium-phosphine chemistry. Synthesis, structure, and spectroscopy of phosphapentadienyl-bridged iridium dimers
1674, ACS, Washington, DC, USA (14):
[3] PENTADIENYL METAL PHOSPHINE CHEMISTRY .16. REACTION CHEMISTRY OF (ETA-3-2,4-DIMETHYLPENTADIENYL)RH(PET3)2 AND (ETA-3-2,4-DIMETHYLPENTADIENYL)RH(PME3)2
BLEEKE, JR
DONALDSON, AJ
ORGANOMETALLICS, 1988, 7 (07) : 1588 - 1596
[4] PENTADIENYL METAL PHOSPHINE CHEMISTRY .8. SYNTHESIS AND SOLUTION DYNAMICS OF (ETA-3-2,4-DIMETHYLPENTADIENYL)RH(PR3)2 COMPLEXES
BLEEKE, JR
DONALDSON, AJ
ORGANOMETALLICS, 1986, 5 (12) : 2401 - 2405
[5] (Fluoroalkyl)phosphine coordination chemistry: Synthesis and structure of {[mu,eta(1),eta(6)-(C6H5)P(C2F5)(2)]Cr(CO)(2)}(2)
Peters, RG
Bennett, BL
Schnabel, RC
Roddick, DM
INORGANIC CHEMISTRY, 1997, 36 (25) : 5962 - 5965
[6] SYNTHESIS, CHARACTERIZATION, AND REACTION CHEMISTRY OF THE NOVEL HETEROBIMETALLIC IRIDIUM PLATINUM COMPLEXES [(PR3)2(CO)IR(MU-H)(MU-ETA-2-ETA-1-CH=CH2)PT(PR'3)2]+[OTF]-
STANG, PJ
HUANG, YH
ARIF, AM
ORGANOMETALLICS, 1992, 11 (02) : 845 - 852
[7] CHEMISTRY OF TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE (TMPP) WITH DIRHODIUM TETRAACETATE - SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF [RH2(MU-O2CCH3)3(ETA-3-MU-TMPP)]0,1+
CHEN, SJ
DUNBAR, KR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 585 - INOR
[8] REACTIONS OF PHOSPHINE, ARSINE, AND STIBINE WITH CARBONYLBIS-(TRIETHYLPHOSPHINE)IRIDIUM(L) HALIDES .1. REACTIONS IN TOLUENE - X-RAY CRYSTAL-STRUCTURES OF [IR(CO)CLH(PET3)2(ASH2)] AND [IR(CO)XH(PET3)2-(MU-ZH2)RUCL2(ETA-6-MEC6H4CHME2-P)](X=BR,Z=P-X=CL,Z=AS)
EBSWORTH, EAV
GOULD, RO
MAYO, RA
WALKINSHAW, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11): : 2831 - 2838
[9] SYNTHESIS OF HIGH-NUCLEARITY CARBONYL-PHOSPHINE CLUSTERS OF PALLADIUM UNDER MILD CONDITIONS AND X-RAY CRYSTAL-STRUCTURE OF PD38(MU-3-CO)4(MU-2-CO)24(PET3)12
MEDNIKOV, EG
EREMENKO, NK
SLOVOKHOTOV, YL
STRUCHKOV, YT
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (03) : 218 - 219
[10] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .88. CARBABORANETUNGSTENIRIDIUM COMPOUNDS - CRYSTAL-STRUCTURE OF THE COMPLEX [WIR(MU-CC6H4ME-4)(CO)2(PET3)2(ETA-5-C2B9H9ME2)]
JEFFERY, JC
RUIZ, MA
SHERWOOD, P
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (09): : 1845 - 1854

← 1 2 3 4 5 →