POLYIMIDES . SYNTHESIS AND POLYMERIZATION OF 4-CARBOXY-2-PIPERIDONE

被引：9

作者：

REIMSCHUESSEL, HK

KLEIN, KP

SCHMITT, GJ

机构：

[1] Corporate Chemical Research Laboratory, Allied Chemical Corporation, Morristown, New Jersey

来源：

MACROMOLECULES | 1969年 / 2卷 / 06期

关键词：

D O I：

10.1021/ma60012a002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new polyimide, poly[(2,5-dioxo-1,3-pyrrolidinediyl)dimethylene], has been obtained by thermal polymerization of 4-carboxy-2-piperidone, which was synthesized from dialkyl itaconate cia cyanomethyl succinate. A possible mechanism of polymerization is discussed that involves isomerization of the 4-carboxy-2-piperidone and step-growth polymerization of the isomerization product. © 1969, American Chemical Society. All rights reserved.

引用

页码：567 / +

页数：1

共 9 条

[1]

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[2]

DAINTON FS, 1958, QUART REV LONDON, V12, P84

[3]

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JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1966, 4 (12PB) :953-+

[5] STRUCTURE OF A NOVEL POLYIMIDE [J].

REIMSCHUESSEL, HK ;

ROLDAN, LG ;

SIBILIA, JP .

JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1968, 6 (3PA2) :559-+

[6] STUDIES ON NEW DERIVATIVES OF EPSILON-CAPROLACTAM [J].

REIMSCHUESSEL, HK ;

SIBILIA, JP ;

PASCALE, JV .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (04) :959-+

[7]

REIMSCHUESSEL HK, IN PRESS

[8]

TAKAHASHI T, 1960, CHEM PHARM BULL, V8, P1106

[9] POLYMERIZATION OF ALPHA-PIPERIDONE BY ALKALI METAL AND CERTAIN ACYL COMPOUNDS [J].

YODA, N ;

MIYAKE, A .

JOURNAL OF POLYMER SCIENCE, 1960, 43 (141) :117-136

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