ASSIGNMENT OF ABSOLUTE-CONFIGURATIONS FROM THE CIRCULAR-DICHROISM SPECTRA OF CYCLIC ETA-4-DIENE COMPLEXES OF FE(CO)3

被引：28

作者：

STEPHENSON, GR ^{[1
]}

HOWARD, PW ^{[1
]}

TAYLOR, SC ^{[1
]}

机构：

[1] ICI BIOL PROD,BILLINGHAM TS23 1LB,CLEVELAND,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 02期

关键词：

D O I：

10.1039/c39910000127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The circular dichroism spectra of a set of 1-substituted tricarbonyl(eta-4-cyclohexadiene)iron(0) complexes with comparable absolute configurations reveal a pattern of bands that correlates with the absolute stereochemistry of the complexes; the nature of the substituents attached at C-1 of the diene is important in the interpretation of the CD spectra of these compounds, since the sign of the highest wavelength band can be reversed for a particular absolute configuration, depending on whether electron-donating or electron-withdrawing substituents are present.

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页码：127 / 129

页数：3

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