INTERSYSTEM CROSSING IN STILBENE EXCIPLEXES

被引：57
作者：
LEWIS, FD
SIMPSON, JT
机构：
[1] Department of Chemistry, Northwestern University, Evanston
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 15期
关键词：
D O I：
10.1021/j100478a018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Intersystem crossing in several long-lived trans-stilbene singlet exciplexes is found to occur via oxygen-independent and oxygen-catalyzed pathways. Rate constants for oxygen-independent intersystem crossing are in the range 1-5 × 107 s-1. Intersystem crossing results in efficient population of the triplet state of trans-stilbene and inefficient population of the other exciplex partner. This result is in accord with Boltzmann controlled population of the two triplet species. The population of triplet species via recombination of solvated radical ions is highly inefficient even though population of triplet stilbene should be exothermic. © 1979 American Chemical Society.
引用
收藏
页码：2015 / 2019
页数：5
相关论文
共 50 条
[21]   Development of an Organic Emitter Exhibiting Reverse Intersystem Crossing Faster than Intersystem Crossing [J].
Okumura, Ryosuke ;
Tanaka, Hiroyuki ;
Shizu, Katsuyuki ;
Fukushima, Shohei ;
Yasuda, Yuka ;
Kaji, Hironori .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (35)
[22]   COMMENTS ON ACTIVATED INTERSYSTEM CROSSING [J].
THOMAZ, MF ;
STEVENS, B .
CHEMICAL PHYSICS LETTERS, 1972, 17 (02) :160-162
[23]   Nanomagnetic Control of Intersystem Crossing [J].
Cohen, Adam E. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (41) :11084-11092
[24]   Enhanced Intersystem Crossing in a Thiohelicene [J].
Bergwinkl, Sebastian ;
Nuernberger, Patrick ;
Dick, Bernhard ;
Kutta, Roger Jan .
CHEMPHOTOCHEM, 2024, 8 (07)
[25]   Recent progress in high-performance thermally activated delayed fluorescence exciplexes based on multiple reverse intersystem crossing channels [J].
Du, Huitian ;
Hao, Yaming ;
Zhang, Xijian ;
Zhang, Shuyuan ;
Liu, Qiang ;
Pang, Zhiyong .
ORGANIC ELECTRONICS, 2025, 136
[26]   FLUORENONE-PHOTOSENSITIZED ISOMERIZATION OF TRANS-STILBENE - INEFFICIENCIES BOTH IN INTERSYSTEM CROSSING AND IN TRIPLET EXCITATION TRANSFER [J].
CALDWELL, RA ;
GAJEWSKI, RP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (02) :532-&
[27]   All-organic fast intersystem crossing assisted exciplexes exhibiting sub-microsecond thermally activated delayed fluorescence [J].
Traskovskis, Kaspars ;
Sebris, Armands ;
Novosjolova, Irina ;
Turks, Maris ;
Guzauskas, Matas ;
Volyniuk, Dmytro ;
Bezvikonnyi, Oleksandr ;
Grazulevicius, Juozas, V ;
Mishnev, Anatoly ;
Grzibovskis, Raitis ;
Vembris, Aivars .
JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (13) :4532-4543
[28]   INTERSYSTEM CROSSING IN PHOTOSYNTHETIC PIGMENTS [J].
BOWMAN, MK .
CHEMICAL PHYSICS LETTERS, 1977, 48 (01) :17-21
[29]   INTERSYSTEM CROSSING IN MOLECULAR DIMERS [J].
BOWMAN, MK ;
NORRIS, JR .
CHEMICAL PHYSICS LETTERS, 1978, 54 (01) :45-48
[30]   INTERSYSTEM CROSSING AND PREDISSOCIATION OF HALOAROMATICS [J].
HUPPERT, D ;
RAND, SD ;
REYNOLDS, AH ;
RENTZEPIS, PM .
JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (03) :1214-1224
12345