A FACILE SYNTHESIS OF NEW TETRAPYRROLE MACROCYCLIC DERIVATIVES - FORMATION OF BIMETALLIC TRANSITION-METAL COMPLEXES

被引：46

作者：

CORRIU, RJP

BOLIN, G

MOREAU, JJE

VERNHET, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Me(hexynyl)CuLi with (Me3Si)2NCH2-C=C-CO2Et followed by treatment with a diacid dichloride gave a facile access to meta-dipyrrolyl benzene or 2,6-dipyrrolyl pyridine derivatives, which were cyclised to tetrapyrrolic macrocycles 7 and 9; further reactions with Pd(acac)2 or Ni(acac)2 led to bimetallic complexes.

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页码：211 / 213

页数：3

相关论文

共 25 条

[1] SAPPHYRINS - NOVEL AROMATIC PENTAPYRROLIC MACROCYCLES [J].

BAUER, VJ ;

CLIVE, DLJ ;

DOLPHIN, D ;

PAINE, JB ;

HARRIS, FL ;

KING, MM ;

LODER, J ;

WANG, SWC ;

WOODWARD, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (21) :6429-6436

[2]

BRINGMANN G, 1982, LIEBIGS ANN CHEM, P1272

[3]

BRINGMANN G, 1982, LIEBIGS ANN CHEM, P1261

[4] SYNTHESIS OF 22 PI-ELECTRON MACROCYCLES - SAPPHYRINS AND RELATED COMPOUNDS [J].

BROADHURST, MJ ;

JOHNSON, AW ;

GRIGG, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (16) :2111-+

[5] SULFUR EXTRUSION REACTIONS APPLIED TO SYNTHESIS OF CORROLES AND RELATED SYSTEMS [J].

BROADHURST, MJ ;

GRIGG, R ;

JOHNSON, AW .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (9-10) :1124-+

[6] SILYLAMINES IN ORGANIC-SYNTHESIS - PREPARATION AND SOME REACTIONS OF N,C-DILITHIOSILYLAMINES [J].

BURNS, SA ;

CORRIU, RJP ;

HUYNH, V ;

MOREAU, JJE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 333 (03) :281-290

[7]

CALLOT HJ, 1975, TETRAHEDRON LETT, P2919

[8] NEW TETRAPYRROLIC MACROCYCLES - 18 AND 20 PI-ELECTRON HOMOPORPHYRINS [J].

CALLOT, HJ ;

SCHAEFFER, E .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (09) :1567-1570

[9]

CALLOT HJ, 1975, J AM CHEM SOC, V97, P6138

[10]

Corriu R. J. P., 1984, J ORGANOMET CHEM C, V276, P61