Calculation of Gurney Parameters for Aqueous Tetraalkylammonium Halides Based on Friedman's Cosphere-Overlap Model

被引：22

作者：

Streng, William H. ^{[1
]}

Wen, Wen-Yang ^{[1
]}

机构：

[1] Clark Univ, Jeppson Lab, Dept Chem, Worcester, MA 01610 USA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 12期

基金：

美国国家科学基金会;

关键词：

Model calculation; Gurney parameters; tetraalkylammonium halides; cosphere-overlap model; heat-capacity parameters;

D O I：

10.1007/BF00647941

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recalculations of the Gurney free-energy parameters A(ij) based on the cosphere-overlap model of Friedman and co-workers have been made using more recent experimental data. Our procedure for calculation seems to be more systematic than those previously reported. The excess energy, entropy, and volume parameters (E(ij), TS(ij), and V(ij)) were also recalculated for some aqueous tetraalkylammonium halides. In addition, the excess-heat-capacity parameters C(ij) are also reported here for the first time. These data are discussed briefly in terms of the structural implications.

引用

页码：865 / 880

页数：16

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