SPECTRAL STUDY OF SOME NEW LOW-SYMMETRY OXOMOLYBDENUM(V) COMPLEXES

被引：19
作者：
PENCE, HE
SELBIN, J
机构：
[1] Coates Chemical Laboratories, Louisiana State University, Baton Rouge
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 02期
关键词：
D O I：
10.1021/ic50072a033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The following new low-symmetry oxomolybdenum(V) complexes were synthesized and characterized by conductance, by magnetic susceptibility, and by infrared, visible-ultraviolet, and epr spectroscopy: MoOX3(β-diketonate)-, where X = Cl or Br, and the β-diketones are benzbyltrifluoroacetone, dibenzoylmethane; hexafluoroacetylacetone, and thenoyltrifluoroacetone. Analysis of the electronic spectral data is carried out in detail and band assignments are made, somewhat securely for the ligand field spectral region and somewhat less certain for the charge-transfer and intraligand-transition spectral region. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码：353 / &
相关论文
共 19 条
[1]   HALIDE AND OXYHALIDE COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].
ALLEN, EA ;
WILLIAMS, RG ;
EDWARDS, DA ;
BRISDON, BJ ;
FOWLES, GWA .
JOURNAL OF THE CHEMICAL SOCIETY, 1963, (OCT) :4649-&
[2]   The Electronic Structure of the Vanadyl Ion [J].
Ballhausen, C. J. ;
Gray, Harry B. .
INORGANIC CHEMISTRY, 1962, 1 (01) :111-122
[3]   ELECTRONIC ABSORPTION SPECTRA OF ACETYLACETONATO COMPLEXES .2. HUCKEL LCAO-MO CALCULATIONS FOR COMPLEXES WITH TRIVALENT TRANSITION METAL IONS [J].
BARNUM, DW .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 22 (3-4) :183-191
[4]  
BISHOP AD, 1962, THESIS LOUISIANA STA
[5]   PARAMAGNETIC RESONANCE STUDIES OF BONDING IN VANADYL AND MOLYBDENYL METAL COMPLEXES [J].
DEARMOND, K ;
GARRETT, BB ;
GUTOWSKY, HS .
JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (03) :1019-+
[6]   ELECTRONIC SPECTRA OF BETA-DIKETONE COMPLEXES .3. ALPHA-SUBSTITUTED BETA-DIKETONE COMPLEXES OF COPPER(II) [J].
FACKLER, JP ;
COTTON, FA ;
BARNUM, DW .
INORGANIC CHEMISTRY, 1963, 2 (01) :97-&
[7]  
FORSTER LS, 1964, J AM CHEM SOC, V86, P300
[8]   ELECTRONIC STRUCTURES AND SPECTRA OF CHROMYL AND MOLYBDENYL IONS [J].
GRAY, HB ;
HARE, CR .
INORGANIC CHEMISTRY, 1962, 1 (02) :363-&
[9]  
Horner Sally M., 1965, INORG NUCL CHEM LETT, V1, P43
[10]   ELECTRON SPIN RESONANCE STUDY OF SOME HALOMOLYBDENYL -TUNGSTENYL AND -VANADYL COMPLEXES IN SOLUTION [J].
KON, H ;
SHARPLES.NE .
JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (01) :105-&
12