SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HOMOLOGOUS SERIES PBMO6X14, X=CL, BR, I

被引：33

作者：

BOSCHEN, S

KELLER, HL

机构：

[1] Kiel, Institut für Anorganische Chemie der Christian-Albrechts-Universität

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1992年 / 200卷 / 3-4期

关键词：

LEAD OCTA-MU-3-HALOGENO-HEXAHALOGENO-OCTAHEDRO-HEXAMOLYBDATE(II); CRYSTAL STRUCTURE; MO6X14-GROUP;

D O I：

10.1524/zkri.1992.200.3-4.305

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The compounds PbMo6X14 with X = Cl(I), Br(II), I(III) were synthesized from corresponding mixtures of lead(II) and molybdenum(II) halides. The crystal structures were determined by X-ray analyses and were refined in the cubic spacegroup Pn3BAR (no. 201, sec. setting). The cell dimensions are I: a = 12.921(1) angstrom, II: a = 13.504(2) angstrom and III: a = 14.429(2) angstrom. The structures described below are isotypic to HgMo6Cl14 although some differences are observed. Structural and crystal chemical relations will be discussed.

引用

页码：305 / 315

页数：11

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