NEW REACTION OF EPOXY ALDEHYDES RESULTING IN THE FORMATION OF EPOXY BETA-PROPIOLACTONES

被引：9

作者：

JEDLINSKI, Z

KOWALCZUK, M

机构：

[1] Institute of Polymers, Polish Academy of Sciences, Zabrze

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 02期

关键词：

D O I：

10.1021/jo01316a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of aluminum alkoxides the α-methyl derivatives of glycidaldehyde were shown to yield mainly epoxy β-propiolactones and, as might have been expected, the corresponding diepoxy esters formed in a Tischenko-Claisen reaction. The structure of the resulting diastereomeric epoxy derivatives of β-propiolactone was established and a correlation was found to exist between their yield and the concentration of the catalyst. Copyright © 1979, American Chemical Society. All rights reserved.

引用

页码：222 / 224

页数：3

共 14 条

[1]

CICHON L, 1966, WIAD CHEM, V20, P641

[2] CHEMISTRY OF DIMETHYLKETENE DIMER .4. POLYESTER AND BETA-LACTONE DIMER OF DIMETHYLKETENE [J].