1,8-DIAZAFLUORENONE AND RELATED-COMPOUNDS - A NEW REAGENT FOR THE DETECTION OF ALPHA-AMINO-ACIDS AND LATENT FINGERPRINTS

被引：79

作者：

GRIGG, R ^{[1
]}

MONGKOLAUSSAVARATANA, T ^{[1
]}

POUNDS, CA ^{[1
]}

SIVAGNANAM, S ^{[1
]}

机构：

[1] HOME OFF FORENS SCI SERV,CENT RES & SUPPORT ESTAB,ALDERMASTON,ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(00)97283-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,8-Diazafluorenone (DFO) reacts with (α-amino acids and their esters via imine formation to give decarboxylated azomethine ylides and ester substituted azomethine ylides respectively. In the presence of N-methylmaleimide these azomethine ylides undergo stereospecific cycloaddition via endotransition states. Analogues of DFO give similar cycloadducts. In the absence of dipolarophiles the α amino acids and DFO give a red fluorescent dye thus providing a sensitive method for detecting latent fingerprints on paper. © 1990.

引用

页码：7215 / 7218

页数：4

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