ONLINE CAPILLARY SUPERCRITICAL-FLUID CHROMATOGRAPHY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY FOR THE ANALYSIS OF ORGANOMETALLIC COMPOUNDS

被引：0

作者：

BLAKE, E ^{[1
]}

RAYNOR, MW ^{[1
]}

CORNELL, D ^{[1
]}

机构：

[1] UNIV NATAL,DEPT GEOL,DURBAN 4001,SOUTH AFRICA

来源：

HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY | 1995年 / 18卷 / 01期

关键词：

CAPILLARY SUPERCRITICAL FLUID CHROMATOGRAPHY; INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY; ONLINE SFC-ICPMS; ORGANOMETALLIC COMPOUNDS;

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Supercritical fluid chromatography with inductively coupled plasma-mass spectrometric detection is a new and useful technique for the analysis of organometallic compounds. An interface has been developed for coupling these techniques. The interface is compact, easy to assemble, and causes minimal disruption to either instrument. A series of organotin, organoarsenic, and organoiron compounds has been used to evaluate the interface and ICPMS as a detector for SFC. The effect of analyte concentration and restrictor temperature on peak intensity has been investigated and the effect of the mobile phase on the plasma has also been studied to assess background interference from changes in the plasma.

引用

页码：33 / 37

页数：5

共 9 条

[1] DETERMINATION OF ORGANOTIN COMPOUNDS BY CAPILLARY SUPERCRITICAL-FLUID CHROMATOGRAPHY WITH INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRIC DETECTION
BLAKE, E
RAYNOR, MW
CORNELL, D
[J]. JOURNAL OF CHROMATOGRAPHY A, 1994, 683 (01) : 223 - 231
[2] OPTIMIZATION OF A FLAME PHOTOMETRIC DETECTOR FOR SUPERCRITICAL-FLUID CHROMATOGRAPHY OF ORGANOTIN COMPOUNDS
DACHS, J
BAYONA, JM
[J]. JOURNAL OF CHROMATOGRAPHY, 1993, 636 (02): : 277 - 283
[3] COMPREHENSIVE METHOD FOR DETERMINATION OF AQUATIC BUTYLTIN AND BUTYLMETHYLTIN SPECIES AT ULTRATRACE LEVELS USING SIMULTANEOUS HYDRIDIZATION EXTRACTION WITH GAS-CHROMATOGRAPHY FLAME PHOTOMETRIC DETECTION
MATTHIAS, CL
BELLAMA, JM
OLSON, GJ
BRINCKMAN, FE
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1986, 20 (06) : 609 - 615
[4] ONLINE SUPERCRITICAL FLUID EXTRACTION AND CHROMATOGRAPHY OF ORGANOTINS WITH PACKED MICROBORE COLUMNS AND FORMIC-ACID MODIFIED CARBON-DIOXIDE
OUDSEMA, JW
POOLE, CF
[J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 344 (10-11): : 426 - 434
[5] PREPARATION OF ROBUST TAPERED RESTRICTORS FOR CAPILLARY SUPERCRITICAL FLUID CHROMATOGRAPHY
RAYNOR, MW
BARTLE, KD
DAVIES, IL
CLIFFORD, AA
WILLIAMS, A
[J]. JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY & CHROMATOGRAPHY COMMUNICATIONS, 1988, 11 (03): : 289 - 291
[6] METAL DETERMINATION AND METAL SPECIATION BY LIQUID-CHROMATOGRAPHY - A REVIEW
ROBARDS, K
STARR, P
[J]. ANALYST, 1991, 116 (12) : 1247 - 1273
[7] EVALUATION OF INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY AS AN ELEMENTAL DETECTOR FOR SUPERCRITICAL FLUID CHROMATOGRAPHY
SHEN, WL
VELA, NP
SHEPPARD, BS
CARUSO, JA
[J]. ANALYTICAL CHEMISTRY, 1991, 63 (14) : 1491 - 1496
[8] DETERMINATION OF TRI-ORGANOTIN AND TETRA-ORGANOTIN COMPOUNDS BY SUPERCRITICAL FLUID CHROMATOGRAPHY WITH INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRIC DETECTION
VELA, NP
CARUSO, JA
[J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1992, 7 (06) : 971 - 977
[9] ELEMENTAL SPECIATION WITH PLASMA-MASS SPECTROMETRY
VELA, NP
OLSON, LK
CARUSO, JA
[J]. ANALYTICAL CHEMISTRY, 1993, 65 (13) : A585 - +

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