RELATIONSHIP OF IMPACT SENSITIVITY WITH STRUCTURE OF ORGANIC HIGH EXPLOSIVES .2. POLYNITROAROMATIC EXPLOSIVES

被引：340

作者：

KAMLET, MJ

ADOLPH, HG

机构：

[1] Naval Surface Weapons Center, White Oak Laboratory, Silver Spring, Maryland

来源：

PROPELLANTS AND EXPLOSIVES | 1979年 / 4卷 / 02期

关键词：

D O I：

10.1002/prep.19790040204

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Impact sensitivities of organic high explosives are primarily functions of the rates of the thermal decomposition processes taking place in the temperature regimes generated under the impact hammer. For classes of explosives with similar decomposition mechanisms, there appear to be statistically significant linear relationships (sensitivity/composition trends) between logarithmic 50% impact heights and values OB100, a measure of oxidant balance. In addition, it is shown that polynitroaromatic explosives containing a C‐H linkage alpha to the aromatic ring are more sensitive as a class than explosives lacking such a linkage. These results are consistent with the finding that products of thermal decomposition of TNT indicate a preferred site of inter‐ and intramolecular oxidative attack to be at the alpha C‐H linkage. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：30 / 34

页数：5

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