DIRECT LOCATION OF THE HYDRIDO LIGANDS IN THE DIANION [H4OS10(CO)24]2- BY A NEUTRON-DIFFRACTION STUDY OF ITS [(PH3P)2N]+ SALT AT 20-K

被引：29

作者：

BASHALL, A

GADE, LH

LEWIS, J

JOHNSON, BFG

MCINTYRE, GJ

MCPARTLIN, M

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[2] POLYTECH N LONDON,SCH CHEM,LONDON N7 8DB,ENGLAND

[3] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hitherto best molecular model for the chemisorption of CO and H-2 on metal surfaces is the decanuclear cluster ion [H4Os10(CO)24]2- 1. All four hydrido ligands are located on the surface of the metal framework; consequently an initiating H...CO interaction can be deduced because of the very tight C - H contacts. [GRAPHICS]

引用

页码：1164 / 1167

页数：4

共 22 条

[21] VERY SHORT OHO HYDROGEN-BONDS IN A BINUCLEAR TRANSITION-METAL COMPLEX - NEUTRON-DIFFRACTION STUDY AT 120-K OF [CO-2(H2N(CH2)2OH)3(H2N(CH2)2O)3][CLO4]3.0.5H2O
JONES, DJ
ROZIERE, J
LEHMANN, MS
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03): : 651 - 655
[22] Selective azide oxidation of 1,2-bis(diphenylphosphino)benzene and related ethylenebis(phosphines) to asymmetric multifunctional phosphorus ligands and formation of rhodium(I) complexes of these ligands. Structural characterization of the prototypical ligand 1-(((trimethylsilyl)imino)diphenylphosphorano)-2-(diphenylphosphino)benzene and its rhodium(I) complex: 1-Ph(2)P=N(SiMe(3))C6H4-2-(Ph(2)P)Rh(CO)Cl
Reed, RW
Santarsiero, B
Cavell, RG
INORGANIC CHEMISTRY, 1996, 35 (15) : 4292 - 4300

← 1 2 3 →