INFRARED AND RAMAN-SPECTRA OF 2-(ALPHA-HYDROXYBENZYL)THIAMINE, 2-(ALPHA-HYDROXYCYCLOHEXYLMETHYL)THIAMINE, THEIR PROTONATED FORMS AND THEIR COMPLEXES WITH ZINC(II), CADMIUM(II) AND MERCURY(II)

被引：9

作者：

HADJILIADIS, N ^{[1
]}

LOULOUDI, M ^{[1
]}

BUTLER, IS ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,QUEBEC,CANADA

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 3-4期

关键词：

D O I：

10.1016/0584-8539(91)80122-Y

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The infrared and Raman spectra of the ligands; 2-(alpha-hydroxybenzyl)thiaminium chloride (HBT), 2-(alpha-hydroxycyclohexylmethyl)thiaminium chloride (HCMT), and their protonated forms. HBT.HCl and HCMT.HCl, as well as of their zwitterionic type complexes Zn(HBT)Cl3, Cd(HBT)Cl3, Hg(HBT)Cl3 and Zn(HCMT)Cl3, Cd(HCMT)Cl3, Hg(HCMT)Cl3, have been recorded in the region 4000-50 cm-1. Several characteristic band have been identified or tentatively assigned and are discussed in relation to the structures of the complexes. It is concluded from the spectra that the complexes are isostructural and that the bonding site of the ligands is the N(1') atom of the pyrimidine moiety.

引用

页码：445 / 453

页数：9

共 50 条

[41] ZINC(II) AND CADMIUM(II) COMPLEXES OF THE POTENTIALLY TRIDENTATE LIGANDS 2-[[2-PYRIDINYLMETHYL)AMINO]METHYL]PHENOL (HSALAMP) AND 2-[[[2-(2-PYRIDINYL)ETHYL]AMINO]METHYL]PHENOL (HSALAEP) - X-RAY CRYSTAL-STRUCTURES OF THE [ZN(SALAMP)(NO3)]2 AND THE [CD(SALAEP)(NO3)]2 DIMERS
TANDON, SS
CHANDER, S
THOMPSON, LK
BRIDSON, JN
MCKEE, V
INORGANICA CHIMICA ACTA, 1994, 219 (1-2) : 55 - 65
[42] Structures and trends of neutral MXxsolvent4-x tetrahedra and anionic [MX4]2- tetrahalometallates of zinc(II), cadmium(II) and mercury(II) with benzopyridine- and benzopyrazine-type N-donor ligands or cations
Slabbert, C.
Rademeyer, M.
CRYSTENGCOMM, 2016, 18 (24): : 4555 - 4579
[43] ASPECTS OF ORGANOCADMIUM CHEMISTRY .3. CHELATE-SUPPORTED ALKYLS AND ARYLS OF ZINC, CADMIUM, AND MERCURY - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[2-((DIMETHYLAMINO)METHYL)PHENYL]MERCURY(II)
ATWOOD, JL
BERRY, DE
STOBART, SR
ZAWOROTKO, MJ
INORGANIC CHEMISTRY, 1983, 22 (23) : 3480 - 3482
[44] POLYOL METAL-COMPLEXES .6. STRUCTURE OF LITHIUM BIS[METHYL ALPHA-L-RHAMNOPYRANOSID-(2,3)-ATO(2-)]CUPRATE(II) TETRAHYDRATE
KLAASSEN, M
KLUFERS, P
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 686 - 688
[45] TRANSITION METAL(II) COMPLEXES OF 1-(ALPHA-HYDROXYNAPHTHYL)-2-(3'-METHYL-5'-MERCAPTO-1',2',4'-TRIAZOLE)-2-AZA-ETHANE
SATPATHY, KC
PANDA, AK
MISHRA, R
CHOPDAR, AP
PRADHAN, SK
TRANSITION METAL CHEMISTRY, 1991, 16 (06) : 628 - 630
[46] Zinc(II) and cadmium(II) complexes based on 2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-(4-methoxyphenyl)pyrimidine-4-carboxylic acid: Synthesis, structure and luminescence
Bushuev, Mark B.
Krivopalov, Viktor P.
Nikolaenkova, Elena B.
Pervukhina, Natalia V.
Naumov, Dmitrii Yu
Rakhmanova, Marianna I.
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (05) : 749 - 752
[47] Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate:: X-ray structure analysis of mer-bis{(E)-2-[N′-(1-pyridin-2-yl-ethylidene)hydrazino]acetato}cobalt(III) tetrafluoroborate
Filipovic, NR
Bacchi, A
Pelizzi, G
Markovic, R
Mitic, D
Andelkovic, KK
JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (17) : 1541 - 1550
[48] H-1,C-13, AND N-15 NMR-SPECTRA OF NI(II) COMPLEXES OF SCHIFF-BASES OF (S)-2-(N-BENZYLPROLYL)AMINOBENZOPHENONE AND ALPHA-MONOSUBSTITUTED GLYCINE AND DETERMINATION OF CONFIGURATION OF THE COMPLEXES BY 2D NOESY SPECTRA
JIRMAN, J
POPKOV, A
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1995, 60 (06) : 990 - 998
[49] Oligomerization of ethylene to linear alpha-olefins by tetrahedral cobalt(II) complexes with 6-(organyl)-2-(imino)pyridyl ligands: Influence of the heteroatom in the organyl group on the catalytic activity.
Bianchini, C
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U758 - U758
[50] 1/1 METAL-COMPLEXES OF BIVALENT COBALT, NICKEL, COPPER, ZINC, AND CADMIUM WITH THE TRIPODAL LIGAND TRIS[2-(DIMETHYLAMINO)ETHYL]AMINE - THEIR STABILITIES AND THE X-RAY CRYSTAL-STRUCTURE OF ITS COPPER(II) COMPLEX SULFATE
ANDEREGG, G
GRAMLICH, V
HELVETICA CHIMICA ACTA, 1994, 77 (03) : 685 - 690

← 1 2 3 4 5 →