MONO-SUBSTITUTION OF IRON PENTACARBONYL CATALYZED BY POLYNUCLEAR IRON CARBONYL ANIONS

被引：56

作者：

BUTTS, SB

SHRIVER, DF

机构：

[1] Department of Chemistry, Northwestern University, Evanston

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)81158-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The specific formation of LFe(CO)4 (L = PPh3, P(OPh)3, P(OMe)3 can be achieved by the reaction of Fe(CO)5 with L in the presence of a catalytic amount of iron carbonyl anion. A convenient synthetic procedure was developed in which the iron carbonyl anion catalyst is generated in situ. It is shown that the mechanism does not proceed by the simple cleavage of the Fe2(CO)82- or Fe3(CO)112- anions, because triphenylphosphine reacts with these anions in the absence of Fe(CO)5 to produce (PPh3)2Fe(CO)3. © 1979.

引用

收藏

页码：191 / 197

页数：7

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