TOPOLOGICAL DEGENERACY OF MAGNETIC ORBITALS IN ORGANIC BIRADICALS MEDIATED BY METAL-IONS - TRIPLET GROUND-STATE IN A TITANIUM(IV) COMPLEX OF SCHIFF-BASE DIQUINONE RADICAL LIGANDS

被引：45

作者：

CANESCHI, A ^{[1
]}

DEI, A ^{[1
]}

GATTESCHI, D ^{[1
]}

机构：

[1] UNIV FIRENZE,DEPT CHEM,VIA MARAGLIANO 75,I-50144 FLORENCE,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000630

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A large intramolecular ferromagnetic interaction is observed in a titanium(IV) complex formed by two tridentate Schiff base semiquinonato radical ligands; this peculiar magnetic behaviour may be rationalised on the basis of the structural properties of the biradical compound.

引用

页码：630 / 631

页数：2

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