SYNTHESIS AND CRYSTAL-STRUCTURE OF KCR0.8AL0.2MO2O8

被引：4

作者：

SEDELLO, O ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,D-24098 KIEL,GERMANY

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 210卷 / 1-2期

关键词：

D O I：

10.1016/0925-8388(94)90158-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of KCr0.8Al0.2Mo208 were prepared and investigated by the X-ray diffractometer technique. It shows a structure type related to trigonal KAlMo2O8, monoclinic NaCrMo2O8 or orthorhombic KInMo2O8, space group C2h6-C2/c; a=17.445 angstrom, b=5.649 angstrom, c=8.997 angstrom, beta=119.37; Z=4. KCr0.8Al0.2Mo2O8 is characterized by isolated MoO4 tetrahedra, isolated (Cr/Al)O6 octahedra and a distorted square antiprism around K+. The crystal structure is discussed with respect to those of related compounds.

引用

页码：331 / 334

页数：4

共 15 条

[1]

Efremov V. A., 1973, Soviet Physics - Crystallography, V17, P1005

[2]

JOHNSON CK, 1965, ORNL3794 REP

[3]

Klevtsov P. V., 1972, Soviet Physics - Crystallography, V17, P474

[4]

KLEVTSOV.RF, 1971, SOV PHYS CRYSTALLOGR, V16, P241

[5]

KLEVTSOVA RF, 1971, SOV PHYS CRYSTALLOGR, V15, P829

[6]

KLEVTSOVA RF, 1975, RUSS J INORG CHEM, V20, P1659

[7]

KRUGER TF, 1992, THESIS U KIEL

[8] CRYSTAL-STRUCTURE OF ALPHA-CUGDW2O8 AND CUNDMO2O8 [J].

MULLERBUSCHBAUM, H ;

SEDELLO, O .

JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 204 (1-2) :237-241

[9] A CONTRIBUTION ON CUPRMO2O8 AND CUTBMO2O8 [J].

MULLERBUSCHBAUM, H ;

SEDELLO, O .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (04) :647-650

[10]

PANNETIER G, 1972, B SOC CHIM FR, P485

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