SYNTHESIS AND CHARACTERIZATION OF IRIDIUM CHLORIDE COMPLEXES .2. USE OF PHENOTHIAZINES WITHOUT N-ALKYL SIDE-CHAIN AS LIGANDS

被引：8

作者：

GOWDA, NMM

ZHANG, L

机构：

[1] Department of Chemistry, Western Illinois University

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 05期

关键词：

D O I：

10.1080/00945719408001304

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iridium complexes Of some phenothiazine derivatives have been prepared in MeOH or EtOH medium. The complexes have been characterized by elemental analyses, molecular weight, magnetic susceptibility, molar conductivity, and spectral data. The molecular formulas of the new complexes are [Ir2(pz)5Cl4(MeOH)]Cl (where pz = phenothiazine), [Ir2(cpz)4]Cl MeOH (where cpz = 2-chlorophenothiazine), [Ir2(apz)5Cl5]Cl .3MeOH (where apz = 2-acetylphenothiazine), [Ir3(dopz)2Cl5(EtOH)][Ir2Cl4(EtOH)2].4EtOH (where dopz = 3,7-dinitro-5-oxophenothiazine) and [Ir(tmpz)5Cl]Cl.EtOH (where tmpz = trifluoromethyl-phenothiazine).

引用

页码：831 / 844

页数：14

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