SECONDARY MOLD METABOLITES .41. STRUCTURE AND BIOSYNTHESIS OF CERCOSPORA-BETICOLA TOXIN (CBT)

被引：15

作者：

ARNONE, A

NASINI, G

MERLINI, L

RAGG, E

ASSANTE, G

机构：

[1] POLITECN MILAN, DIPARTIMENTO CHIM POLITECN, CTR CNR SOSTANZE ORGAN NAT, PIAZZA L DAVINCI 32, I-20133 MILAN, ITALY

[2] UNIV MILAN, DIPARTIMENTO SCI MOLEC AGROALIMENTARI, SEZ CHIM, I-20133 MILAN, ITALY

[3] UNIV MILAN, IST PATOL VEGETALE, I-20133 MILAN, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 01期

关键词：

D O I：

10.1039/p19930000145

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structure of Cercospora beticola toxin (CBT) 1, a phytotoxic metabolite, was elucidated on the basis of mass, H-1 NMR, C-13 NMR and 2D NMR (C-13, C-13 COSY and H-1, H-1 ROESY) spectra and from biosynthetic evidence obtained from incorporation of [1-C-13]acetate and (1,2-C-13]acetate. The product is a 2:2 complex with Mg of a compound derived from the coupling of two octaketide-derived reduced anthraquinone and xanthone moieties.

引用

页码：145 / 151

页数：7

共 25 条

[1] CERCOSPORA-BETICOLA TOXIN - A REASSESSMENT OF SOME INVITRO EFFECTS [J].

ADUCCI, P ;

COZZELLA, ML ;

DIGIORGIO, D ;

FOGLIANO, V ;

MARRA, M .

PLANT SCIENCE, 1992, 84 (01) :53-57

[2] SECONDARY MOLD METABOLITES .15. STRUCTURE ELUCIDATION OF RUBELLIN-A AND RUBELLIN-B, 2 NOVEL ANTHRAQUINONE METABOLITES FROM MYCOSPHAERELLA-RUBELLA [J].

ARNONE, A ;

CAMARDA, L ;

NASINI, G ;

ASSANTE, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02) :255-260

[3]

ARNONE A, 1989, GAZZ CHIM ITAL, V119, P35

[4] COMPARATIVE-EVALUATION OF PHOTODYNAMIC EFFICIENCY OF SOME NATURAL QUINONOID FUNGAL TOXINS [J].

ARNONE, A ;

ASSANTE, G ;

CARONNA, T ;

DIMODUGNO, V ;

NASINI, G .

PHYTOCHEMISTRY, 1988, 27 (06) :1669-1674

[5]

ARNONE A, IN PRESS PHYTOCHEMIS

[6] SCREENING OF GENUS CERCOSPORA FOR SECONDARY METABOLITES [J].

ASSANTE, G ;

LOCCI, R ;

CAMARDA, L ;

MERLINI, L ;

NASINI, G .

PHYTOCHEMISTRY, 1977, 16 (02) :243-247

[7]

ASSANTE G, COMMUNICATION

[8] CERCOSPORA-BETICOLA TOXIN INHIBITS VANADATE-SENSITIVE H-+ TRANSPORT IN CORN ROOT MEMBRANE-VESICLES [J].

BLEIN, JP ;

BOURDIL, I ;

ROSSIGNOL, M ;

SCALLA, R .

PLANT PHYSIOLOGY, 1988, 88 (02) :429-434

[9]

FRANDSEN N. O., 1955, Zucker, V8, P469

[10] STRUCTURE OF THE SODIUM AND POTASSIUM-ION ACTIVATED ADENOSINE-TRIPHOSPHATASE INHIBITOR-L-681,110 [J].

HENSENS, OD ;

MONAGHAN, RL ;

HUANG, LY ;

ALBERSSCHONBERG, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) :3672-3679

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