CESIUM OXYGEN COADSORPTION ON RU(001)

被引:25
|
作者
SHI, H
JACOBI, K
ERTL, G
机构
[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-1000 Berlin 33
关键词
D O I
10.1016/0039-6028(92)91332-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Cs and O coadsorption on Ru(001) was studied by high-resolution electron energy loss spectroscopy (HREELS) and UV photoelectron spectroscopy (UPS). The Cs monolayer exhibits a square-root 3 structure in LEED. The coadsorption of oxygen was studied at 95 and 220 K. At small oxygen doses a broad band of Cs-O vibrations is found at 25+/-3 meV and a change of the LEED pattern into a split (2 X 2). At higher oxygen coverage evidence for dioxygen species and the Ru-O vibration is observed.
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页码:682 / 686
页数:5
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