SIMPLE PREPARATION OF THE BINARY METAL-SULFUR CLUSTERS [MO3S13]2- AND [MO2S12]2- FROM MOO42- IN PRACTICALLY QUANTITATIVE YIELD

被引:108
作者
MULLER, A
BHATTACHARYYA, RG
PFEFFERKORN, B
机构
[1] Fakultät für Chemie, Universität Bielefeld, Bielefeld, D-4800
来源
CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 02期
关键词
D O I
10.1002/cber.19791120240
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simple Preparation of the Binary Metal‐Sulfur Clusters [MO3S13]2− and [Mo2SI2]2− from MoO42− in Practically Quantitative Yield (NH4)2[Mo3S(S2)6] 2 H2O (2) could be isolated by heating an aqueous solution of MoO42− with (NH42− Sx, for several hours. The anions of both compounds are in equilibrium under the stated conditions. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
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页码:778 / 780
页数:3
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