POLYFUNCTIONAL CARBOSILANES AND ORGANOSILICON COMPOUNDS - SYNTHESIS VIA GRIGNARD REACTIONS

被引：31

作者：

BRONDANI, DJ ^{[1
]}

CORRIU, RJP ^{[1
]}

ELAYOUBI, S ^{[1
]}

MOREAU, JJE ^{[1
]}

MAN, MWC ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,DEPT CHIM ORGAN FINE,RP,CNRS,UNITE MIXTE 44,F-34095 MONTPELLIER 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

关键词：

TRIALKOXYSILYLATION REACTION; (TRIETHOXYSILYL)METHYL GRIGNARD; CARBOSILANES; CROSS-COUPLING REACTION;

D O I：

10.1016/S0040-4039(00)60358-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The THF solutions of (triethoxysilyl)methyl magnesium chloride are stable at low temperature. At 20-degrees-C, the Grignard reagent underwent intermolecular condensation, providing a simple synthesis of cyclic carbosilanes derivatives. The cross-coupling reaction with organic halides also afforded a facile route to a variety of trifunctional organosilicon compounds.

引用

页码：2111 / 2114

页数：4

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