IODOSOBENZENE AND PERSULFATE OXYGENATION OF SATURATED-HYDROCARBONS CATALYZED BY DIPHOSPHINO COMPLEXES OF RUTHENIUM(III)

被引：10

作者：

BRESSAN, M ^{[1
]}

FORTI, L ^{[1
]}

MORVILLO, A ^{[1
]}

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-35131 PADUA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 211卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)85605-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydroxylation and/or ketonization of alkanes (adamantane, cyclo-octene, hexane) is achieved by using iodosobenzene or aqueous mono-persulfate at room temperature in the presence of catalytic amounts of ruthenium(III)-diphosphino complexes dissolved in dichloromethane. On the basis of the kinetic behavior, different oxidizing metal species are proposed for the oxidations with mono-persulfate and with iodosobenzene.

引用

页码：217 / 220

页数：4

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