KINETICS AND MECHANISM OF SUBSTITUTION-REACTIONS OF 4-COORDINATE AND 5-COORDINATE IRIDIUM(I) COMPLEXES - DETECTION OF A STABLE REACTION INTERMEDIATE

被引：7
作者：
LOUW, WJ
SINGLETON, JE
机构：
[1] National Chemistry Reseach Laboratory, South African Council for Scientific and Industrial Research, Pretoria
来源：
INORGANICA CHIMICA ACTA | 1978年 / 27卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)87255-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The substitution reactions of the four- (X = Cl) and five- (X = I, SCN) coordinate complexes CODIr(phen)X with ethylenediamine have been studied kinetically. The mechanism for the five-coordinate system was dissociative. A stable four- or five-coordinate intermediate CODIr(phen)(en)+ hat been detected in the substitution reaction the four-coordinate system. © 1978.
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页码：21 / 26
页数：6
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