BLACK FOAM FILMS OF BINARY AQUEOUS-SOLUTIONS OF GELATIN AND A SURFACTANT

被引:0
作者
DERKACH, SR [1 ]
IZMAILOVA, VN [1 ]
ZOTOVA, KV [1 ]
机构
[1] MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 117234,USSR
来源
COLLOID JOURNAL OF THE RUSSIAN ACADEMY OF SCIENCES | 1991年 / 53卷 / 06期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For different-types of surfactants - anionic (sodium dodecylsulfate), cationic (cetypyridinium chloride), and nonionic (oxyethylated tridecanol), a study has been made of their influence on the properties of free films of gelatin-based foams. It has been shown that the film type and the region of film existence for binary solutions of gelatin and surfactant are determined by the structural-rheological properties of the adsorbed layers (the modulus of elasticity and the plastic viscosity). Thermodynamic parameters have been determined for black films formed from a gelatin/surfactant/electrolyte (NaCl) system. The contact angles are smaller than 1-degrees, and the additional tension is on the order of 10(-3) mN/m. The contact angles of black films in binary solutions decrease with increasing surfactant concentration, as do the rheological parameters of the adsorbed layers.
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页码:856 / 861
页数:6
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