GROWTH OF 1,3,5-TRIAMINO-2,4,6-TRINITROBENZENE (TATB) .1. ANISOTROPIC THERMAL-EXPANSION

被引：141
作者：
KOLB, JR
RIZZO, HF
机构：
[1] Lawrence Livermore Laboratory, University of California, Livermore, California
来源：
PROPELLANTS AND EXPLOSIVES | 1979年 / 4卷 / 01期
关键词：
D O I：
10.1002/prep.19790040104
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Expansion of TATB is studied on a molecular level by means of x‐ray crystallography. Continuous monitoring of the cell constants of TATB between 214 K and 377 K allows calculation of a volume change of +5.1% for this molecular system. Expansion of the pure material is almost exclusively a function of a 4% linear increase in the c axis (the perpendicular distance between sheets of hydrogen‐bonded TATB). Calculated from these data, the volume coefficient of thermal expansion for crystalline TATB is 30.4 × 10−5 K−1. The structural features of crystalline TATB and its anisotropic thermal‐expansion behaviour are compared with those of graphite and boron nitride. Two other crystalline products in the bulk TATB are either actual polymorphs of TATB or impurities. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：10 / 16
页数：7
相关论文
共 25 条
[1]  
Jackson C.L., Wing J.F., J. Am. Chem. Soc., 9, (1887)
[2]  
Jackson C.L., Wing J.F., J. Am. Chem. Soc., 10, (1888)
[3]  
Benziger T.M., Rohwer R.K., (1967)
[4]  
Benziger T.M., Rohwer R.K., Urizar M.J., (1973)
[5]  
Cady H.H., Larson A.C., The crystal structure of 1,3,5-triamino-2,4,6-trinitrobenzene, Acta Crystallographica, 18, 3, (1965)
[6]  
Johnson C.K.
[7]  
Herold A., Marzluf B., Perio P., C. R. Hebd. Seances Acad. Sci., 246, (1958)
[8]  
Pease R.S., An X-ray study of boron nitride, Acta Crystallographica, 5, (1952)
[9]  
Ryzhenkov A.P., (1969)
[10]  
Thompson R., Progress in Boron Chemistry, 2, (1970)
123