THE FORMATION AND AN UNUSUAL DIMERIZATION OF 2-MESITYL-1,1-BIS(TRIMETHYLSILYL)SILENE

被引：34

作者：

KREMPNER, C ^{[1
]}

REINKE, H ^{[1
]}

OEHME, H ^{[1
]}

机构：

[1] UNIV ROSTOCK,FACHBEREICH CHEM,D-18051 ROSTOCK,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期

关键词：

D O I：

10.1002/anie.199416151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me3Si)3SiC(OH)Mes. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1615 / 1618

页数：4

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