THE FORMATION AND AN UNUSUAL DIMERIZATION OF 2-MESITYL-1,1-BIS(TRIMETHYLSILYL)SILENE

被引：34
|
作者：
KREMPNER, C [1 ]
REINKE, H [1 ]
OEHME, H [1 ]
机构：
[1] UNIV ROSTOCK,FACHBEREICH CHEM,D-18051 ROSTOCK,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期
关键词：
D O I：
10.1002/anie.199416151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me3Si)3SiC(OH)Mes. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：1615 / 1618
页数：4
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