THERMODYNAMICS OF THE ELECTRON AND THE PROTON

被引:439
作者
BARTMESS, JE
机构
[1] Department of Chemistry, University of Tennessee, Knoxville
关键词
D O I
10.1021/j100076a029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The currently accepted conventions for the thermodynamics of the electron do not follow the proper statistical mechanics equations. The correct values are here obtained from numerical solution of the Fermi-Dirac statistical mechanics equations, yielding an entropy at 298.15 K of 22.734 J/mol.K (5.434 cal/mol.K) and an integrated heat capacity at the same temperature of 3.145 kJ/mol.K (0.752 kcal/mol). The effect that this would have, based on the current thermochemical conventions, on the thermodynamics of the proton, and of all other gaseous ions, is noted.
引用
收藏
页码:6420 / 6424
页数:5
相关论文
共 23 条
[1]   ON ACIDS AND BASES - COMMENT [J].
BURSEY, MM .
MASS SPECTROMETRY REVIEWS, 1990, 9 (05) :503-504
[2]   THE 1986 CODATA RECOMMENDED VALUES OF THE FUNDAMENTAL PHYSICAL CONSTANTS [J].
COHEN, ER ;
TAYLOR, BN .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1987, 92 (02) :85-95
[3]  
DOUGLAS B, 1983, CONCEPTS MODELS INOR, P220
[4]   The quantisation of ideal single atom gases [J].
Fermi, E .
ZEITSCHRIFT FUR PHYSIK, 1926, 36 (11/12) :902-912
[5]  
FRANKLIN JL, 1969, NSRDSNBS26
[6]   The free energy of electron gas [J].
Gordon, AR .
JOURNAL OF CHEMICAL PHYSICS, 1936, 4 (10) :678-679
[7]  
HENCHMAN M, 1990, S ATOMIC SURFACE PHY, P217
[8]  
HENCHMAN M, 1991, FUNDAMENTALS GAS PHA, P285
[9]  
Krestov G. A, 1991, THERMODYNAMICS SOLVA
[10]  
KRESTOV GA, 1966, RADIOKHIMYIA, V6, P218