FUNCTIONALIZATION OF SILICA-GEL - APPLICATION FOR THE CATALYTIC-OXIDATION OF ALKANES

被引：39

作者：

KURUSU, Y ^{[1
]}

NECKERS, DC ^{[1
]}

机构：

[1] BOWLING GREEN STATE UNIV,CTR PHOTOCHEM SCI,BOWLING GREEN,OH 43403

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 06期

关键词：

D O I：

10.1021/jo00006a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silica gel, functionalized by N,N-dimethyl-3-aminopropyl)trimethoxysilane and complexed with Fe-(II) or other metal ions in the presence of O2 was effective for the aerobic, room temperature oxidation of a C-H bond in cyclohexane. The products were cyclohexanol and cyclohexanone.

引用

页码：1981 / 1983

页数：3

共 15 条

[1]

Barton D. H. R., 1989, ACTIVATION FUNCTIONA, P281

[2] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .4. THE GIF SYSTEM FOR SELECTIVE OXIDATION USING MOLECULAR-OXYGEN [J].

BARTON, DHR ;

BOIVIN, J ;

GASTIGER, M ;

MORZYCKI, J ;

HAYMOTHERWELL, RS ;

MOTHERWELL, WB ;

OZBALIK, N ;

SCHWARTZENTRUBER, KM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (06) :947-955

[3] A NEW AND EFFICIENT BIOMIMETIC SYSTEM FOR HYDROCARBON OXIDATION BY DIOXYGEN USING MANGANESE PORPHYRINS, IMIDAZOLE, AND ZINC [J].

BATTIONI, P ;

BARTOLI, JF ;

LEDUC, P ;

FONTECAVE, M ;

MANSUY, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (10) :791-792

[4] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[5] STRUCTURAL CHARACTERIZATION BY EXAFS SPECTROSCOPY OF THE BINUCLEAR IRON CENTER IN PROTEIN-A OF METHANE MONOOXYGENASE FROM METHYLOCOCCUS-CAPSULATUS (BATH) [J].

ERICSON, A ;

HEDMAN, B ;

HODGSON, KO ;

GREEN, J ;

DALTON, H ;

BENTSEN, JG ;

BEER, RH ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2330-2332

[6]

FOX BG, 1988, J BIOL CHEM, V263, P10553

[7]

JIN RH, UNPUB J POLYM SCI A

[8]

KAYL GW, 1973, TABLES PHYSICAL CHEM, P225

[9]

KHENKIN AM, 1989, NEW J CHEM, V13, P669

[10] A MODEL FOR METHANE MONO-OXYGENASE - DIOXYGEN OXIDATION OF ALKANES BY USE OF A MU-OXO BINUCLEAR IRON COMPLEX [J].

KITAJIMA, N ;

FUKUI, H ;

MOROOKA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (07) :485-486

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